Transition metal complexes of an isatinic quinolyl hydrazone

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Transition metal complexes of an isatinic quinolyl hydrazone

BACKGROUND The importance of the isatinic quinolyl hydrazones arises from incorporating the quinoline ring with the indole ring in the same compound. Quinoline ring has therapeutic and biological activities. On the other hand, isatin (1H-indole-2,3-dione) and its derivatives exhibit a wide range of biological activities. Also, the indole ring occurs in Jasmine flowers and Orange blossoms. Recen...

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The ligational behavior of an isatinic quinolyl hydrazone towards copper(II)- ions

BACKGROUND The importance of the isatinic quinolyl hydrazones arises from incorporating the quinoline ring with the indole ring. Quinoline ring has therapeutic and biological activities whereas, the indole ring occurs in Jasmine flowers and Orange blossoms. As a ligand, the isatin moiety is potentially ambidentate and can coordinate the metal ions either through its lactam or lactim forms. In a...

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STUDIES OF TRANSITION METAL COMPLEXES WITH 2N-QUINOLYL- AND 2N-ISOQUINOLYL- 1,1,3,3-TETRAMETHY LGUANIDINES

Ligands derived from 8-quinoline, 6-quinoline, 1 -isoquinoline, and 5-isoquinoline were synthesized. These compounds have been used as ligands for complexation of transition metals, such as copper(II) and nickel(II). According to the spectrosocopic data, copper(II) cation forms (I: 1) and (I:2) complexes with 2-(8-quinoly1)-l,l,3,3- tetramethylguanidine and 2- (I '-isoquinoly1)- 1,1,3,3-tetr...

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studies of transition metal complexes with 2n-quinolyl- and 2n-isoquinolyl- 1,1,3,3-tetramethy lguanidines

ligands derived from 8-quinoline, 6-quinoline, 1 -isoquinoline, and 5-isoquinoline were synthesized. these compounds have been used as ligands for complexation of transition metals, such as copper(ii) and nickel(ii). according to the spectrosocopic data, copper(ii) cation forms (i: 1) and (i:2) complexes with 2-(8-quinoly1)-l,l,3,3- tetramethylguanidine and 2- (i '-isoquinoly1)- 1,1,3,3-te...

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Ligand substitution reactions of a phenolic quinolyl hydrazone; oxidovanadium (IV) complexes

BACKGROUND Quinoline ring has therapeutic and biological activities. Quinolyl hydrazones constitute a class of excellent chelating agents. Recently, the physiological and biological activities of quinolyl hydrazones arise from their tendency to form metal chelates with transition metal ions. In this context, we have aimed to study the competency effect of a phenolic quinolyl hydrazone (H2L; pri...

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ژورنال

عنوان ژورنال: Chemistry Central Journal

سال: 2011

ISSN: 1752-153X

DOI: 10.1186/1752-153x-5-35